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Chemistry · General chemistry I · Worked example

Find the molarity of a solution

11.7 g of NaCl is dissolved in water to make 500.0 mL of solution. What is the molarity of the solution?

11.7 g⁡ NaCl in 500.0 mL

Convert the solute to moles

The molar mass of NaCl is 22.99 + 35.45 = 58.44 g/mol, so 11.7 g is 11.7 ÷ 58.44 = 0.200 mol.

11.7 g⁡ NaCl×1 mol NaCl58.44 g⁡ NaCl=0.200 mol NaCl
11.7 g⁡ NaCl×1 mol NaCl58.44 g⁡ NaCl=0.200 mol NaCl

Convert the volume to liters

Molarity uses liters of solution: 500.0 mL is 0.5000 L.

500.0 mL=0.5000 L

Divide moles by liters

0.200 mol ÷ 0.5000 L = 0.400 mol/L, written 0.400 M. The answer has three significant figures, like 11.7 g.

M=0.200 mol0.5000 L=0.400 M

Check the size of the answer

About a fifth of a mole in half a liter is about two fifths of a mole per liter, or 0.4 M. The answer fits.

Result

The solution is 0.400 M NaCl.

Your turn

How many grams of NaCl do you need to make 250.0 mL of 0.150 M NaCl?

Show the answer and explanation

2.19 g.

Moles needed: 0.2500 L × 0.150 mol/L = 0.0375 mol. Mass: 0.0375 mol × 58.44 g/mol = 2.19 g.

0.2500 L×0.150 mol1 L×58.44 g⁡1 mol=2.19 g⁡
0.2500 L×0.150 mol1 L×58.44 g⁡1 mol=2.19 g⁡

Keep exploring

Open the solution in Solutions & concentration and change the volume to 250.0 mL: the same salt in half the volume doubles the molarity, to 0.801 M.

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